Organic chemistry – Page 7
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OpinionOrganic chemists should place their trust in machine learning’s black box
Submitting to the higher power of abstraction can strengthen our insights
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FeatureThe messy chemistry that led to life
To understand how chemistry became biology, some chemists are eschewing simple reactions to study complex systems with many reactants and products. Rachel Brazil peers through the tangle
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ResearchBoron-doped olympicenes are surprisingly stable
By possessing useful electronic properties, boraolympicenes could have potential applications in organic electronics
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ResearchExtraordinary crystal structure displays abiotic foldamer with unprecedented complexity
Four aromatic oligoamide helix-turn-helix units assemble in organic solvent into an abiotic architecture with quaternary-like structure
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ResearchSoapbark tree’s biosynthetic pathway for vaccine adjuvant saponins
Researchers use genome mining and bioengineering techniques to map out route
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ResearchSkeletal editing provides a simple route to access isoquinolines
Direct nitrogen atom insertion into a broad range of indenes and cyclopentadienes
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FeatureEditing the structure of molecules
Nina Notman meets the chemists expanding the toolbox of reactions capable of adding, deleting and switching single atoms in rings at the heart of organic molecules
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Research‘Dynamic bonds’ reshape the rules of aromaticity and chirality
Discoveries could contribute to new understanding of organic chemistry, triggering applications in catalysis and materials science
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ResearchHarvesting water from the air with organic crystals
Discovery could lead to novel technologies for fighting water scarcity
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ResearchWater works as medium for reactions that reduce carboxylic acids
Catalytic system works on a wide range of acid substrates and doesn’t require precious metals or air and moisture intolerant reagents
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ResearchAI identifies molecules from their featureless visible spectrum
Forget about trying to interpret peaks and let machine learning identify organic compounds from their entirely smooth visible spectrum
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ResearchPure conjugated polymer nanowires crystallised using oligomers
Oligomers used to induce crystallisation in parent conjugated polymers for the first time
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WhitepaperHow catalysis may enable ‘wish-list’ reactions
Download this free white paper now and discover how solutions to challenging problems can be solved using catalysis, and how Sinocompound can help provide access to less available catalysts/ligands
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OpinionN-heterocyclic carbenes are more than passive spectators
The practical importance of N-heterocyclic carbenes continues to grow
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WebinarRobots in the lab – learn how automation can streamline your workflow
The future of lab automation is promising. Join us to find out answers to the most important questions, and to contribute your knowledge and experience to the discussion.
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ResearchFirst synthesis of 1-azahomocubane shows nitrogen can take the strain
Chemists overcome synthetic challenges to finally incorporate a nitrogen atom into the homocubane skeleton
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ResearchGel capsules make reactions with organolithiums simpler and safer
Low-cost gels improve the handling and storage of traditionally dangerous organometallics, expanding applications and possibilities in synthesis
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ResearchSurprise as electric fields found to cleave bond homolytically
Study also uncovers that the reaction rate in a field increases linearly with the solvent dielectric constant
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ResearchTetraquinoline is the newest member of the nitrogen macrocycle family
The new saddle-shaped macrocycle shows catalytic activity and affinity to zinc cations